Investigations on the micellization of amphiphilic dendritic copolymers: From unimers to micelles
نویسندگان
چکیده
منابع مشابه
Micellization of block copolymers
This article deals with recent progress including the author’s work in the field of block copolymer self-assembly in solution and on solid surfaces. The synthesis methods for producing block copolymers with well-defined structures, molecular weights and composition are outlined with emphasis on ionic and controlled free radical polymerization techniques. A general overview of the preparation, c...
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The thermal stability of a self-assembled micelle was remarkably enhanced by a topology effect. Linear poly(butyl acrylate)-block-poly(ethylene oxide)-block-poly(butyl acrylate) (1) and the cyclized product, poly(butyl acrylate)-block-poly(ethylene oxide) (2), were self-assembled to form flower-like micelles. By means of viscometry, the critical micelle concentrations were determined to be 0.13...
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15 صفحه اولComplex micelles from the self-assembly of amphiphilic triblock copolymers in selective solvents.
The self-assembled microstructures of amphiphilic block copolymers depend on the selectivity of solvents for each block. By changing the selectivity of solvents, defined in terms of the repulsive interactions between the solvent and the hydrophilic/hydrophobic particles, an extensive simulation study on the spontaneous formation of complex micelles from amphiphilic triblock copolymers in a dilu...
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We report an extensive simulation study on the spontaneous formation of complex micelles from coilrod-coil amphiphilic triblock copolymers in dilute solution resulting from solvent selectivity. The amphiphilic molecule is built from one hydrophilic block on each side and a hydrophobic block in the middle. The rigidity of the rod block is introduced by adding a bond-bending potential of the angl...
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ژورنال
عنوان ژورنال: Journal of Colloid and Interface Science
سال: 2018
ISSN: 0021-9797
DOI: 10.1016/j.jcis.2017.12.070